Study on the Flotation Beneficiation of Baganuur Lignite

Authors

  • Byambaa Munkhtsetseg Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar, Mongolia
  • Yunchang Lig China University of Mining and Technology, Xuzhou, China
  • Damdindorj Mungunnaran Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar, Mongolia
  • Gandandorj Shiirav Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar, Mongolia
  • Barnasan Purevsuren Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar, Mongolia
  • Yaowen Xing China University of Mining and Technology, Xuzhou, China
  • Budeebazar Avid Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar, Mongolia

Keywords:

lignites, flotation, collector, clean coal, tailings

Abstract

Baganuur lignite has high ash and moisture contents, making long-distance transportation uneconomical and limiting its export potential. Therefore, beneficiation is required to improve its quality and utilization value. Research on lignite beneficiation in Mongolia remains relatively limited. Furthermore, lignite is generally considered difficult to upgrade by flotation because of its high oxygen-containing functional groups and inherently hydrophilic surface. Therefore, this study investigated the mineralogical characteristics, mineral distribution, and flotation beneficiation of Baganuur lignite.

                The results showed that clay minerals and pyrite were finely and uniformly disseminated throughout the coal matrix. Among the flotation tests, the best result was obtained using Collector 1100, producing a clean coal with a yield of 12.81% and an ash content of 11.93%. However, the overall flotation performance remained relatively poor because fine mineral particles coated the coal surface, gangue minerals were readily entrained into the concentrate, and coarse coal particles were difficult to float. Following a pre-desliming treatment, the flotation performance was significantly improved, producing a clean coal with a yield of 39.52% and an ash content of 12.62%.

                The study demonstrated that Baganuur lignite possesses an inherently hydrophilic surface and poor floatability. In addition, the organic matter and inorganic minerals are finely and uniformly distributed, making their separation particularly challenging. The results further indicate that the flotation performance of lignite is strongly influenced by particle size distribution, surface hydrophobicity and hydrophilicity, particle–bubble and particle–particle interactions, as well as the electrokinetic properties of the coal surface. These findings provide a mechanistic basis for understanding the flotation behavior of low-rank coals and for developing more effective beneficiation strategies for Baganuur lignite.

Багануурын ордын хүрэн нүүрсний флотацын судалгаа

Хураангуй. Багануурын хүрэн нүүрс нь үнслэг өндөртэй, чийг ихтэй тул хол газар тээвэрлэхэд ашиггүй, экспортлох боломж хомс учир баяжуулан чанарыг сайжруулах шаардлагатай. Манай орны хэмжээнд хүрэн нүүрсний баяжуулалтын судалгаа харьцангуй бага хийгдсэн, нөгөө талаас хүрэн нүүрс нь их хэмжээний хүчилтөрөгч агуулдаг тул баяжуулахад амаргүйд тооцоогддог. Иймээс энэхүү судалгаагаар Багануурын хүрэн нүүрсний эрдсийн найрлага, тархалтын онцлог болон баяжуулалтын судалгаа хийлээ. Багануурын нүүрсэнд шаварлаг эрдэс болон пирит нарийн ширхэгтэйгээр жигд тархсан бөгөөд цуглуулагч 1100-г ашиглан флотацаар баяжуулахад 12.81%-ийн гарцтай, 11.93%-ийн үнстэй баяжмал гарсан нь хамгийн сайн үр дүн байв. Туршилтын явцад эрдсийн ширхгүүд нүүрсний гадаргууг бүрхэх, баяжмалтай хамт хөвөх, мөн том ширхэгтэй нүүрсийг хөвүүлэхэд хүндрэлтэй байсан зэргээс флотацын үр ашиг харьцангуй сул байлаа. Харин шламгүйжүүлснээр 39.52%-ийн гарцтай, 12.62%-ийн үнстэй баяжмал гарган авлаа. Судалгаанаас харахад хүрэн нүүрс нь гидрофил шинж чанартай, хөвөх чадвар муу бөгөөд органик ба органик бус эрдсүүдийн хэмжээ маш нарийн, жигд тархалттай тул тэдгээрийг салгах нь хүндрэлтэй байв. Хүрэн нүүрсний флотац нь нүүрсний ширхэглэлийн хэмжээ, гадаргуугийн гидрофоб ба гидрофил шинж, гадаргуу хоорондын харилцан үйлчлэл болон гадаргуугийн цахилгаан шинж чанараас ихээхэн хамааралтай болохыг уг судалгаа харууллаа.

Түлхүүр үг: хүрэн нүүрс, флотац, цуглуулагч, баяжмал, хаягдал

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References

[1] V.Vijayaraghavan, E.V. Lau, Ankit Goyal, Xiaodong Niu, A. Garg, L. Gao, Design of explicit models for predicting the efficiency of heavy oil-sand detachment process by floatation technology, Measurement 137 (2019) 122-19. https://doi.org/10.1016/j.measurement.2019.01.074

[2] D. Tao, Role of bubble size in flotation of coarse and fine particles-a review, Separ.Sci. Technol. 39 (4) (2004) 741-760. https://doi.org/10.1081/SS-120028444

[3] W. Xia, C. Ni, G. Xie, Effective flotation of lignite using a mixture of dodecane and 4 dodecylphenol (DDP) as a collector, Coal Prep. 36 (5) (2015) 262-271. https://doi.org/10.1080/19392699.2015.1113956

[4] R. Jia, G.H. Harris, D.W. Fuerstenau, An improved class of universal collectors for the flotation of oxidized and/or low-rank coal, Int. J. Miner. Process. 58 (1) (2000) 99-118. https://doi.org/10.1016/S0301-7516(99)00024-1

[5] W.C. Xia, J. Yang, C. Liang, B. Zhu, The effects of conditioning time on the flotation of oxidized coal, Energy Sources 36 (1) (2014) 31-37. https://doi.org/10.1080/15567036.2012.697095

[6] Намхайноров, Ж., Мөнхцэцэг, Б., Шийрав, Г., ЯаоВэн Шинг, Пүрэвсүрэн, Б., Авид, Б., Навчцэцэг, Н, Багануур ба Шивээ-Овоогийн нүүрсний баяжуулалтад үзүүлэх цуглуулагчийн нөлөөлөл, Химийн нийгэмлэгийн бүтээл, 2024, 19, 59-71.

[7] T. Grzybek, R. Pietrzak, H. Wachowska, X-ray photoelectron spectroscopy study of oxidized coals with different sulphur content, Fuel Process. Technol. 77 (1) (2002) 1-7. https://doi.org/10.1016/S0378-3820(02)00058-9

[8] T. Grzybek, R. Pietrzak, H. Wachowska, The influence of oxidation with air in comparison to oxygen in sodium carbonate solution on the surface composition of coals of different ranks, Fuel 85 (7) (2006) 1016-1023. https://doi.org/10.1016/j.fuel.2005.09.017

[9] G. Ateşok, M.S. Çelik, A new flotation scheme for a difficult-to-float coal using pitch additive in dry grinding, Fuel 79 (12) (2000) 1509-1513. https://doi.org/10.1016/S0016-2361(00)00012-0

[10] Huang, G., Xu, J., Geng, P., Li, J. Carrier Flotation of Low-Rank Coal with Polystyrene. Minerals 2020, 10, 452. https://doi.org/10.3390/min10050452

[11] Yang, A., Liao, Y., An, M., Cao, Y., Yang, Z., Ren, H., Su, H., Zou, Q., Chen, L. Effect of Ultrasonic Pretreatment on Flocculation Filtration of Low-Rank Coal Slurry. Molecules 2022, 27, 6460. https://doi.org/10.3390/molecules27196460

[12] Zhang, Q., Niu, C., Bu, X., Bilal, M., Ni, C., Peng, Y. Enhancement of Flotation Performance of Oxidized Coal by the Mixture of Laurylamine Dipropylene Diamine and Kerosene. Minerals 2021, 11, 1271. https://doi.org/10.3390/min11111271

[13] Han, H., Liu, A.,Wang, H. Effect of Hydrodynamic Cavitation Assistance on Different Stages of Coal Flotation. Minerals 2020, 10, 221. https://doi.org/10.3390/min10030221

[14] Liao, Y., Song, X., An, M., Yang, Z., Hao, X., Ren, H. Effect of Dodecane-Oleic Acid Collector Mixture on the Evolution of Wetting Film between Air Bubble and Low-Rank Coal. Minerals 2021, 11, 58. https://doi.org/10.3390/min11010058

[15] Yao, N., Liu, J., Sun, X., Liu, Y., Chen, S. Wang, G. A Rational Interpretation of the Role of Turbulence in Particle-Bubble Interactions. Minerals 2021, 11, 1006. https://doi.org/10.3390/min11091006

[16] Zhang, H., Xi, P., Zhuo, Q., Liu,W. Construction of Molecular Model and Adsorption of Collectors on Bulianta Coal. Molecules 2020, 25, 4030. https://doi.org/10.3390/molecules25174030

[17] Xing, Y., Xu, M., Gui, X., Cao, Y., Babel, B., Rudolph, M., Weber, S., Kappl, M., Butt, H.-J. The application of atomic force microscopy in mineral flotation. Adv. Colloid Interface Sci. 2018, 256, 373-392. https://doi.org/10.1016/j.cis.2018.01.004

[18] Zeng, W., Zhang, G., Shi, Q., Ou, L. Effects and Mechanism of Fe3+ on Flotation Separation of Feldspar and Epidote with Sodium Oleate at Natural pH. Separations 2022, 9, 110. https://doi.org/10.3390/separations9050110

[19] Wu, D., Wang, M., Zeng, J., Yao, J., Jia, C., Zhang, H., Li, J. Preparation and Characterization of Graphene from Refined Benzene Extracted from Low-Rank Coal: Based on the CVD Technology. Molecules 2021, 26, 1900. https://doi.org/10.3390/molecules26071900

[20] Chang, Z., Chen, X., Peng, Y. The interaction between diesel and surfactant Triton X-100 and their adsorption on coal surfaces with different degrees of oxidation. Powder Technol. 2019, 342, 840-847. https://doi.org/10.1016/j.powtec.2018.10.047

[21] Wang, Y., Zhou, Y., He, Q., Xing, Y., Bao, X., Gui, X., Wang, L. Research on Mechanisms of Improving Flotation Selectivity of Coal Slime by Adding Sodium Polyphosphate. Minerals 2022, 12, 1392. https://doi.org/10.3390/min12111392

[22] Zhu, C., Xing, Y., Xia, Y., Wang, Y., Li, G., Gui, X. Flotation intensification of low-rank coal using a new compound collector. Powder Technol. 2020, 370, 197-205. https://doi.org/10.1016/j.powtec.2020.05.027

[23] Zhou,W.,Wang, S.,Wang, L., Cai, C., Li, J., Liu, L., Zhu, J., Min, F. Study on Dispersion and Mixing Mechanism of Coal Slime Particles in Jet Mixing Flow Field. Minerals 2023, 13, 13. https://doi.org/10.3390/min13010013

[24] Xia, Y., Fang, D., Qu, P., Li, Y. Interfacial Adhesion between Fatty Acid Collectors and Hydrophilic Surfaces: Implications for Low-Rank Coal Flotation. Molecules 2022, 27, 4392. https://doi.org/10.3390/molecules27144392

[25] Hu, X., Tong, Z., Sha, J., Bilal, M., Sun, Y., Gu, R., Ni, C., Li, C., Deng, Y. Effects of Flotation Reagents on Flotation Kinetics of Aphanitic (Microcrystalline) Graphite. Separations 2022, 9, 416. https://doi.org/10.3390/separations9120416

[26] Zhang, L., Sun, X., Li, B., Xie, Z., Guo, J., Liu, S. Experimental and molecular dynamics simulation study on the enhancement of low rank coal flotation by mixed collector. Fuel 2020, 266, 117046. https://doi.org/10.1016/j.fuel.2020.117046

[27] Bao, X., Xing, Y., Liu, Q., Liu, J., Dai, S., Gui, X., Li, J., Yang, Z. Investigation on mechanism of the oleic acid/methyl oleate/diesel ternary compound collector in low-rank coal flotation. Fuel 2022, 320, 123894. https://doi.org/10.1016/j.fuel.2022.123894

[28] Liao, Y., Yang, Z., An, M., Ma, L., Yang, A., Cao, Y., Chen, L., Ren, H. Alkanes-esters mixed collector enhanced low rank coal flotation: Interfacial interaction between oil drop and coal particle. Fuel 2022, 321, 124045. https://doi.org/10.1016/j.fuel.2022.124045

[29] Xue, Z., Dong, L., Li, H., Fan, M., Ren, Z., Liu, A., Fan, P., Bao,W. Study on the mechanism of flotation of coal gasification fine slag reinforced with naphthenic acids. Fuel 2022, 324, 124557. https://doi.org/10.1016/j.fuel.2022.124557

[30] Li, Y., Zhang, D., Zhang, Z., Molecular dynamics simulation of fatty acid collectors with different carbon chain lengths on the surface of low-rank coal. Chem Phys Lett, 2022, 806, 140068. https://doi.org/10.1016/j.cplett.2022.140068

[31] Wen, B., Xia, W., Sokolovic, J.M., Recent advances in effective collectors for enhancing the flotation of low rank/oxidized coals. Powder Technol., 2017, 319, 1-11. https://doi.org/10.1016/j.powtec.2017.06.030

[32] Vilas'o-Cadre, J.E., Avila-M'arquez, D.M., Reyes-Domínguez, I.A., Blanco-Flores, A., Guti'errez-Casta˜neda, E.J., Coal flotation in a low-rank carbonaceous mineral using 3- phenyl-1-propanol as a collector reagent, Fuel, 2021, 304, 121363. https://doi.org/10.1016/j.fuel.2021.121363

[33] Tian, Q., Zhang, Y., Li, G., Wang, Y., Application of Carboxylic Acid in Low-Rank Coal Flotation. Int J Coal Prep Util., 2019, 39(1), 44-53. https://doi.org/10.1080/19392699.2017.1297299

[34] Xia, Y., Zhang, R., Xing, Y., Gui, X., Improving the adsorption of oily collector on the surface of low-rank coal during flotation using a cationic surfactant: An experimental and molecular dynamics simulation study. Fuel 2019, 235, 687-95.https://doi.org/10.1016/j.fuel.2018.07.059

[35] Jia, R., Harris, G.H., Fuerstenau, D.W., An improved class of universal collectors for the flotation of oxidized and/or low-rank coal. Int J Miner Process., 2000, 58(1), 99-118. https://doi.org/10.1016/S0301-7516(99)00024-1

[36] Xia, Y., Xing, Y., Gui, X., Cao, Y., Interaction between hydrocarbon oil and hydrophilic mineral surfaces: A chemical force microscopy and molecular dynamics simulation study, Fuel, 2022, 323, 124402. https://doi.org/10.1016/j.fuel.2022.124402

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2025-12-30

How to Cite

Munkhtsetseg, B., Lig, Y., Mungunnaran, D., Shiirav, G., Purevsuren, B., Xing, Y., & Avid, B. (2025). Study on the Flotation Beneficiation of Baganuur Lignite. Journal of the Mongolian Chemical Society, 20(1), 31-45. https://doi.org/10.5564/jmcs.v20i1.5648

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How to Cite

Munkhtsetseg, B., Lig, Y., Mungunnaran, D., Shiirav, G., Purevsuren, B., Xing, Y., & Avid, B. (2025). Study on the Flotation Beneficiation of Baganuur Lignite. Journal of the Mongolian Chemical Society, 20(1), 31-45. https://doi.org/10.5564/jmcs.v20i1.5648

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