Mongolian Journal of Chemistry https://www.mongoliajol.info/index.php/MJC <p>Published by the Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences.</p> <p>The Mongolian Journal of Chemistry is included on <a title="DOAJ" href="https://doaj.org/toc/2414-0082" target="_blank" rel="noopener">DOAJ</a>,&nbsp;&nbsp;<a title="EBSCO" href="https://www.ebscohost.com/discovery" target="_blank" rel="noopener">EBSCO Discovery Service</a>,&nbsp;&nbsp;<a title="Google Scholar" href="https://scholar.google.com" target="_blank" rel="noopener">Google Scholar</a>,&nbsp; &nbsp;<a title="MJC" href="https://app.dimensions.ai/discover/publication?and_facet_source_title=jour.1148887" target="_blank" rel="noopener">Dimensions</a>,&nbsp;&nbsp;<strong>CAS databases, <a title="CNKI" href="https://enscholar.cnki.net/journal/search" target="_blank" rel="noopener">CNKI</a>,&nbsp;</strong>and&nbsp;<a title="MJC - Scopus" href="https://www.scopus.com/sourceid/21100941615" target="_blank" rel="noopener"><strong>Scopus</strong></a></p> Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences en-US Mongolian Journal of Chemistry 2226-6739 <p>Copyright on any research article in the <strong>Mongolian Journal of Chemistry</strong> is retained by the author(s).</p> <p>The authors grant the <strong>Mongolian Journal of Chemistry</strong> a license to publish the article and identify itself as the original publisher.</p> <p><a href="http://creativecommons.org/licenses/by/4.0/" rel="license"><img style="border-width: 0;" src="https://i.creativecommons.org/l/by/4.0/88x31.png" alt="Creative Commons Licence"></a><br>Articles in the <strong>Mongolian Journal of Chemistry</strong> are Open Access articles published&nbsp;under a <a href="http://creativecommons.org/licenses/by/4.0/" rel="license">Creative Commons Attribution 4.0 International License</a> CC BY.</p> <p>This license permits use, distribution and reproduction in any medium, provided the original work is properly cited.</p> A quantum chemical study of the interaction of carboxylic acids with DMSO https://www.mongoliajol.info/index.php/MJC/article/view/1407 <p>Quantum chemical computational methods, which use quantum mechanics and molecular dynamics theory, have developed rapidly in the past few decades, and quantum chemical computation has penetrated almost all fields of chemistry. Hydrogen bonds are ubiquitously common weak intermolecular interactions. Moreover, the bonding mechanism of hydrogen bonds is considered to be different from that of chemical bonding. Because of the difficulty of experimental studies, a more accurate calculation of hydrogen bonding from theory is a more convenient and direct method to understand hydrogen bonding. Density functional theory (DFT) is the most widely used general function in quantum chemical calculations, giving accurate results for most chemical systems. In this paper, the geometries of the hydrogen-bonded dimer complex of acetic acid and DMSO was structurally optimized and potential energy surface was determined. The geometries of four related hydrogen-bonded dimer complexes were fully optimized using the M06-2X/6-311++G (3d, 2p) exchange-correlation functional with DFT-D3(BJ) empirical dispersion correction. We found that hydrogen bonding is a mixture of electrostatic interactions and covalent bonding, and that hydrogen bonding is a kind of force with different percentages of electrostatic and covalent character, rather than a special force independent of chemical bonding. Thus, more clearly defining our inherent classification of forces between substances provides a new perspective for our future study of weak interactions such as hydrogen bonding.</p> Mu Ren Ao Rigele Na Shun Narantsogt Natsagdorj Copyright (c) 2022 Mu Ren, Ao Rigele, Na Shun, Narantsogt Natsagdorj http://creativecommons.org/licenses/by/4.0 2022-05-27 2022-05-27 23 49 10.5564/mjc.v23i49.1407 Efficiency of KOH-activated carbon for removal of heavy metal pollution from water https://www.mongoliajol.info/index.php/MJC/article/view/1406 <p>The study to reduce heavy metals pollution from water using the KOH-activated carbon was studied the factors affecting the adsorption capacities of Cu(II) and Pb(II), in particular, initial metals concentration, pH of the solution, and contact time in static conditions. Using X-ray photoelectron spectroscopy and FTIR analysis to determine the elemental composition and surface functional groups of the activated carbon surface, the presence of oxygen-related functional groups was observed. The maximum adsorption capacities were 135.8 mg g<sup>-1</sup> and 31.0 mg g<sup>-1</sup> for removal of lead and copper solutions with the initial concentration of 300 mg L<sup>-1</sup> of metal at 318 K, respectively. The removal percentage was found to be higher for Pb (II) when compared with Cu (II).</p> Narandalai Byamba-Ochir Nazgul Muratbyek Narangarav Tumen-Ulzii Ariunaa Alyeksandr Nasantogtokh Oyunchimeg Copyright (c) 2022 Narandalai Byamba-Ochir, Nazgul Muratbyek, Narangarav Tumen-Ulzii, Ariunaa Alyeksandr, Nasantogtokh Oyunchimeg http://creativecommons.org/licenses/by/4.0 2022-05-27 2022-05-27 23 49 10.5564/mjc.v23i49.1406 Development technology of starter cultures using lactic acid bacteria isolated from fermented Camel milk with cholesterol lowering ability https://www.mongoliajol.info/index.php/MJC/article/view/1404 <p>The aim of the study is to develop a technology of starter cultures for fermented milk using new strains of lactic acid bacteria isolated from Mongolian traditional fermented camel milk. “<em>Khoormog</em>” samples are collected from Inner Mongolia, China. Totally 230 <em>Lactobacillus </em>strains are isolated and screened by acid-, bile- tolerance, lactose decomposition and acid production ability. The cholesterol lowering abilities and adhesiveness on Caco-2 are evaluated. The top 2 strains are identified as <em>Lactobacillus</em><em> plantarum</em>. These 2 strains are prepared as the starter cultures in milk fermentation. The development technology of starter cultures is studied.</p> Sarengaole Bayinjirigala Tsend-Ayush Chuluunbat Jirigala Bayin Bilige Menghe Copyright (c) 2022 Sarengaole, Tsend-Ayush Chuluunbat, Bayinjirigala, Menghebilige http://creativecommons.org/licenses/by/4.0 2022-05-30 2022-05-30 23 49 10.5564/mjc.v23i49.1404